You can print documents from Google Classroom through Canon PRINT Inkjet / SELPHY on your iOS device. Follow the steps below to print from Google Classroom.
Access the IJ Cloud Printing Center
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On the main screen of Canon PRINT Inkjet / SELPHY, tap More.

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Tap Cloud.

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Tap Start to sign in to the IJ Cloud Printing Center.

If your printer is not registered with the IJ Cloud Printing Center, you will need to register it.
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Tap Google Classroom.

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You will be prompted to sign into your Google Account.

Select your account from the list. If it isn't listed, or if you want to use a different account, select Use another account and then sign in when prompted.
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You will be asked to provide permission for your printer to access your Google Account. Select Allow on each prompt.

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After allowing each request, you will be prompted to confirm your choices. Select Allow to proceed.

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After a few moments, you will see the option to print your class list as well as various folders that have been set up. Selecting Print my class list will print out all of the classes that you are a member of.

Selecting this option will present you with various print options, such as the paper size and number of copies. Tap Print when ready.

You will be asked if you want to start printing. Select OK to print, or Cancel to return to the print options.
If you select OK, the class list will be sent to the printer. This may take a few minutes.

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You will be prompted to return to the app top or the app list. If you want to print additional items from Google Classroom, select Go to app top. If you want to use a different cloud service, select Go to app list.

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If you choose Go to app top, select a folder from the main screen. Then, select Assigned, Turned in, or Returned.

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Select an item that you want to print. Specify your options as desired, then tap Print. Select OK when asked to start printing.